I will prove that $\frac{2x}{\pi}<\sin x < x$, for all $0<x<\frac{\pi}{2}$.
Proof:
First I'll use the fact that if functions $f,g$ are continuous on $[a,b)$ and diffrentiable on $(a,b)$, and satisfies $f(a)\leq g(a)$, $f'(x)\leq g'(x)$ for all $x\in (a,b)$, then $f(x)\leq g(x)$ to all $x\in [a,b)$.
We are ready to prove $\sin x < x$ for all $x\in [0,\frac{\pi}{2}]$. Let us define $f(x)=\sin x-x$. We will get
$$f(0)=0$$
$$f'(x)=\cos x -1$$
Hence, $f(x)\leq 0$ for all $x\in [0,\frac{\pi}{2}]$. To prove that instead of "$\leq$" there is "$<$" we use Rolle's theorem. Suppose that there is $x_0\in (0,\frac{\pi}{2}]$ for which $f(x_0)=0$; then all Rolle's theorem conditions are satisfied on the closed interval $[0,\frac{\pi}{2}]$, and therefore there must be a point $c\in (0,x_0) $ such that $f'(c)=0$. But $f'(x)=0$ iff $\cos x =1$, which then $x=\frac{\pi}{2}$, and that is a contradiction. We deduce that for all $x_0\in (0,\frac{\pi}{2}]$ there $f(x_0)<0$, and hence we have that for all $x\in (0,\frac{\pi}{2})$, we have $\sin x <x$.
Now we define $g(x)=\frac{2x}{\pi}-\sin x$. And we have that $g(0)=0$. But in this case we have some problem:
$$g'(x)=\frac{2}{\pi}-\cos x$$
When $\frac{2}{\pi}-\cos x=0$, we have $\cos x= \frac{2}{\pi}$, we deduce that there is another solution which is obtained on $(0,\frac{\pi}{2})$.
If we look more carefully, we will see that there is only one solution for that equation, in other words the derivative is zero only in one point. Also, we notice that
$$g(\frac{\pi}{2})=\frac{2}{\pi}\frac{\pi}{2}-\sin (\frac{\pi}{2})=1-1=0$$
Again, all Rolle's theorem conditions are satisfied for $g(x)$ on the closed $[0,\frac{\pi}{2}]$ (and in every sub interval). It is impossible that for $x_0\in (0,\frac{\pi}{2})$ there $g(x_0)=0$. Now, if $x_1\in (0,\frac{\pi}{2})$ it is also impossible to have $g(x_1)>0$, because from the continuity of $g(x)$, $g(x)$ must have zero on $(0,\frac{\pi}{2})$. Therefore, for all $x\in (0,\frac{\pi}{2})$ we have $g(x)<0$, thus $\frac{2x}{\pi}<\sin x$.