I believe that this is essentially a question of showing that the radius of the circumcircle is less than $\sqrt{2}/2$ because the largest triangle that can fit in the unit square is the right-triangle with unit sides, hypotenuse of $\sqrt{2}$ and circumradius of $\sqrt{2}/2$. Let's demonstrate how easy it is to calculate this in the complex plane. Given three random points, say $z_{1,2,3}$, we can determine the circumcenter, $z_c$ and radius, $r$ as shown here.
$$
z_c\
\;=\;\frac{\left|
\begin{array}{ccc}
z_1 & |z_1|^2 & 1 \\
z_2 & |z_2|^2 & 1 \\
z_3 & |z_3|^2 & 1
\end{array}
\right|}
{\left|
\begin{array}{ccc}
z_1\ & {z_1}^*\ & 1 \\
z_2\ & {z_2}^*\ & 1 \\
z_3\ & {z_3}^*\ & 1
\end{array}
\right|}
$$
and
$$
r=|z_c-z_1|=|z_c-z_2|=|z_c-z_3|
$$
These calculations can probably be calculated by hand, but most likely will be done on a computer. I did just that in a matter of just six lines of code (in Matlab). You can then go on to plot the triangle, circumcircle, and overlay a unit square (though it may not be in the correct orientation).