Questions tagged [lewis-structure]

For questions about determining Lewis structures (or their validity) for different chemical species. Do not use this tag if your question is about determining [oxidation-state] or [formal-charges], use the other respective tags instead.

A Lewis structure (usually referred to as a Lewis dot structure) is a simple model or approximation used to determine the bonding behavior of atoms within molecules. Dots represent valence electrons for each atom while solid lines represent shared pair of electrons between atoms (i.e. covalent bonds).

For example, this is the Lewis structure of the water molecule $\ce{H2O}$ (See also simple Wikipedia):

Lewis structure of water

Notice the two lone pairs (= 4 electrons) on the oxygen atom shown by dots and the two bond pairs (O-H) shown by solid lines.

Lewis structures may also be drawn for charged species. Here is the Lewis structure for the ammonium ion:

Lewis structure of the ammonium ion

Notice that a solid line with an arrow indicates a coordinate covalent bond, with the arrow pointing from the donor atom to the receiver atom.

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The Lewis structure of HNO3

So I was checking the structure of nitric acid in Wikipedia, however I couldn't quite fathom why it looked like that because it seemed to contradict the following statement: A Lewis structure with small or no formal charges is preferred over a…
Zafer Cesur
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Lewis Structure on (CH3)2NO?

I've been taking an chemistry class online (for fun only) and one of the questions in the homework threw me a bit. Here's the wording: "Draw the Lewis structure for a nitrogen atom attached to. two methyl groups ($\ce{CH3}$) and one oxygen…
Andrew
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What is the Lewis Structure for CO?

In many sites I see that they take $\ce{C}$ with valence 4, bur our teacher takes it with valence 2. With what valence should I take $\ce{C}$?
user13411
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What is the correct Lewis structure of NH3O?

Choose the most appropriate Lewis structure for $\ce{NH3O}$ among the two: and The oxygen in the second case has 3 nonbonding pairs around it. I chose the first as an answer, yet the second seems to be the correct one. Can anyone please explain…
Hasan Saad
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The Lewis structure for NCO-

I was having trouble drawing the Lewis structure for $\ce{NCO^-}$. I found this image online: But why is structure number one preferred over structure number two? Why does carbon prefer to have a triple bond with nitrogen, rather than have a double…
Saturn
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How is the Nitrate Ion (NO3) formed?

I understand how the nitrite $\ce{NO2}$ ion can be formed and have a negative charge, but the nitrate $\ce{NO3}$ ion is confusing me. I made some simple drawings to try to explain what I don't understand: Does the "electron from outside" that the…
Lucas M.
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Lewis structure of Cl2SO

Why is it that the Lewis structure of $\ce{Cl_2SO}$ has a total of $24$ valence electrons? I thought that the number of valence electrons should be $2\times7 + 1\times6 + 1\times6 = 26$.
okarin
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Is it possible to use the school supplied algorithm to build the Lewis diagram of the iodate ion?

I am upgrading the grade 12 chemistry credit and have to use the school supplied algorithm to build the Lewis diagram of $\ce{IO3-}$ ion. It seems to me that iodine oxidation state in this ion should be 5, therefore it would have one single and two…
aiag
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Lewis Structure For H2SO4

When I was drawing the lewis structure for $\ce{H2SO4}$ I got this configuration, now I know this isn't the best configuration but I don't see whats wrong with it. The number of valence electrons is right, the free electrons are on the most…
Arowaaron
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Structure of phosphorus pentachloride

Why is the shape of $\ce{PCl5}$ trigonal bipyramidal? All the $\ce{Cl}$ atoms must be at equal distances forming a star like shape. However, in the actual shape, the distance between the $\ce{Cl}$ atoms in the equatorial position is less than the…
Jamil Ahmed
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Sulfur trioxide structure

What resonance structure is the most abundant in sulfur trioxide: the one with one double and two single, the one with two double and one single or the one with all three double bonds? Is it actually correct to write an expanded octet when it is not…
EJC
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Lewis Structures - Peripheral Octets

1) Which Lewis structure is preferential of the two below? EN considerations suggest the first structure. Size/charge density suggests the second one; the second structure would likely be more stable because if we think of the halide series of…
Dissenter
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With molecular formula, how do I know if it linear or one element surrounded by other elements?

If I was given a molecular formula (i.e, PoOBr2), how do I know if the Lewis structure is linear (4 in-a-row, basically a straight line) OR it is an element surrounded by other 3 elements? I know the answer for this is Po in the central and…
Knox777
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Bond angle and bond lengths in Arginine

Based on the Lewis structure of arginine, the terminal primary amine attached to the guanidine group seems to be $\mathrm{sp^3}$ hybridized and trigonal pyramidal. Also, in quantum mechanical computations, it is shown that all carbon-nitrogen…
Cyclopropane
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Linear algebra in Lewis structures?

In general, I have come across a phenomenon in chemistry where solutions to certain types of problems can often seem frustrating when trying to work out by hand, as they seem to depend on each other far too much, but are actually easily…
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