Here is a slightly different take on this where we use generating
functions and the method of annihilated coefficient extractors to
verify the claim.
Recall that the species for ordered labelled set partitions is
$$\mathfrak{S}(\mathfrak{P}_{\ge 1}(\mathcal{Z}))$$
which gives the exponential generating function
$$\sum_{n\ge 0} a_n \frac{z^n}{n!}
= \frac{1}{1-z} \circ (\exp(z)-1)
= \frac{1}{2-\exp(z)} = \frac{1}{2}\frac{1}{1-\exp(z)/2}.$$
Introduce $Q(z)$ the exponential generating function for the sum so
that
$$Q(z) = \sum_{n\ge 0} \frac{z^n}{n!}
\sum_{q=0}^n \left[n\atop q\right] a_q.$$
Recall the species of permutations marked by cycle count which is
$$\mathfrak{P}(\mathcal{U}\mathfrak{C}_{\ge 1}(\mathcal{Z}))$$
so that it has the generating function
$$\exp\left(u \log\frac{1}{1-z}\right)$$
and we have
$$\left[n\atop q\right] = n! [z^n] [u^q] \exp\left(u \log\frac{1}{1-z}\right).$$
Substitute this into $Q(z)$ to obtain
$$Q(z) = \sum_{n\ge 0} \frac{z^n}{n!}
\sum_{q=0}^n a_q \times n!
[z^n] \frac{1}{q!} \left(\log\frac{1}{1-z}\right)^q
\\ =
\sum_{q\ge 0} \frac{a_q}{q!}
\sum_{n\ge q} z^n [z^n] \left(\log\frac{1}{1-z}\right)^q.$$
The inner sum is the promised annihilated coefficient extractor and
hence simplifies to
$$Q(z) = \sum_{q\ge 0}
\frac{a_q}{q!} \left(\log\frac{1}{1-z}\right)^q$$
Compare this with the generating function of the $a_q$ to obtain
$$Q(z) =
\frac{1}{2-\exp\left(\log\frac{1}{1-z}\right)}
= \frac{1}{2 - 1/(1-z)} = \frac{1-z}{2(1-z)-1} =
\frac{1-z}{1-2z}.$$
The conclusion is that
$$n! [z^n] Q(z) = n! (2^n-2^{n-1}) = n! \times 2^{n-1}.$$
There is another annihilated coefficient extractor at this
MSE link.
Addendum. Here is a slightly different version of the proof.
Recall once more the species of permutations marked by cycle count
which is
$$\mathfrak{P}(\mathcal{U}\mathfrak{C}_{\ge 1}(\mathcal{Z}))$$
so that it has the generating function
$$\exp\left(u \log\frac{1}{1-z}\right)$$
and in particular
$$\sum_{n\ge q} \left[n\atop q\right] \frac{w^n}{n!}
= \frac{1}{q!} \left(\log\frac{1}{1-w}\right)^q.$$
Continuing, recall the species of set partitions marked by the number
of sets which is
$$\mathfrak{P}(\mathcal{U}\mathfrak{P}_{\ge 1}(\mathcal{Z}))$$
so that it has the generating function
$$\exp\left(u (\exp(z)-1)\right)$$
and in particular
$$\sum_{n\ge q} {n\brace q} \frac{w^n}{n!}
= \frac{1}{q!} \left(\exp(w)-1\right)^q.$$
We have by inspection that
$$a_q = \sum_{p=1}^q p! \times {q\brace p}.$$
Introduce the exponential generating function $P(z)$ of the sum we
want to compute so that
$$P(z) = \sum_{n\ge 1} \frac{z^n}{n!}
\sum_{q=1}^n \left[n\atop q\right] a_q
= \sum_{n\ge 1} \frac{z^n}{n!}
\sum_{q=1}^n \left[n\atop q\right]
\sum_{p=1}^q p! \times {q\brace p}.$$
Reverse the order of summation to get
$$\sum_{p\ge 1} p! \sum_{q\ge p} {q\brace p}
\sum_{n\ge q} \left[n\atop q\right] \frac{z^n}{n!}.$$
We recognize the closed form of the inner sum (partitions into $q$
cycles) and substitute it into this last term to get
$$\sum_{p\ge 1} p! \sum_{q\ge p} {q\brace p}
\frac{1}{q!} \left(\log\frac{1}{1-z}\right)^q$$
The new inner sum also has a simple closed form (partitions into $p$
sets) composed with the logarithmic term. Applying this we obtain
$$\sum_{p\ge 1} p! \times
\frac{1}{p!}
\left(\exp\log\frac{1}{1-z} - 1\right)^p
= \sum_{p\ge 1}
\left(\frac{1}{1-z} - 1\right)^p
\\ = \sum_{p\ge 1}
\left(\frac{z}{1-z}\right)^p
= \frac{z/(1-z)}{1-z/(1-z)} = \frac{z}{1-2z}.$$
We once more obtain
$$n! [z^n] P(z) = n! [z^n] \frac{z}{1-2z}
= n! [z^{n-1}] \frac{1}{1-2z}
= n! \times 2^{n-1}.$$
The discrepancy between $Q(z)$ and $P(z)$ is due to the fact that the latter does not include a term for $n=0.$ There is no doubt that these two proofs are trivial variations on one another, but the second one is explicit about the dependence on the Stirling numbers of the second kind.