Gödel's original proof of the Completeness Theorem for first-order logic proves it in the equivalent form :
a formula $\varphi$ is satisfiable or $\varphi$ is refutable (i.e.$\vdash \lnot \varphi$).
Assuming classical logic, someone can exhibit an example of first-order formula $\varphi$ for which we are not able to decide if it is provable (i.e.$\vdash \varphi$) or if there is a counterexample (i.e.$\lnot \varphi$ is satisfiable) ? In other words, a formula $\varphi$ for which we are not able to decide if it is valid or not ?
Added March 1st
Following Carl's answer, an example of a sentence like the above can be costructed in the following way; ref to Elliott Mendelson, Introduction to Mathematical Logic (4th ed - 1997), Ch.4: Axiomatic Set Theory [page 225-on] :
(i) let $\mathcal N$ the formula obtained by the conjunction of the following axioms for $\mathsf {NBG}$ : Axiom T, Axiom D, Axiom N, Axioms B1-B7, Axiom U, Axiom P, Axiom S, Axiom I, Axiom AC, Axiom Reg (no axiom shemas), after having "unwinded" all the set-theoretic definitions (like : $\emptyset$ and $\subseteq$) and after having replaced in the above formulas all occurences of $\in$ with a binary predicate symbol $R$;
(ii) let $RH$ the formula expressing in the language of $\mathsf {NBG}$ the Riemann Hypothesis, subject to the same "translation".
Then :
$\mathcal N \land \lnot RH$
is an example of formula for which we do not know if it is satisfiable or if it is refutable.