1.) Elementary numbers
The elementary functions were defined by Liouville ([Ritt 1948]). Ritt ([Ritt 1948] p. 60) defined the elementary numbers and asked the problem whether some simple transcendental equations have solutions that are elementary numbers.
Lin and Chow proved, assuming Schanuel's conjecture is true, that no irreducible algebraic equation of both $z$ and $e^z$ have solutions except $0$ that are elementary numbers or explicit elementary numbers respectively.
And Chow, assuming Schanuel's conjecture is true, and Khovanskii proved that the algebraic equations that aren't solvable in radicals cannot be solved by explicit elementary numbers.
Therefore, there are real numbers that aren't elementary numbers or explicit elementary numbers respectively.
Which kinds of equations of elementary functions can have elementary solutions?
Polynomials with degree $5$ solvable in elementary functions?
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2.) Closed-form numbers
If we ask for solutions that are closed-form numbers, we have to ask for solutions in closed form, e.g. in terms of Special functions.
If we ask for closed-form numbers, we have to define which set of functions we allow.
We know that there are equations whose solutions cannot be represented in terms of certain known Special functions, e.g. Lambert W, Generalized Lambert W or HyperLambert W.
What are the closed-form inverses of $x \sinh(x), x \cosh(x), x \tanh(x), x\ \text{sech}(x), x \coth(x), x\ \text{csch}(x)$?
What are the closed-form inverses of $x+\sinh(x)$, $x+\cosh(x)$?
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[Chow 1999] Chow, T.: What is a closed-form number. Am. Math. Monthly 106 (1999) (5) 440-448
[Khovanskii 2014] Khovanskii, A.: Topological Galois Theory - Solvability and Unsolvability of Equations in Finite Terms. Springer 2014
[Khovanskii 2019] Khovanskii, A.: One dimensional topological Galois theory. 2019
[Khovanskii 2021] Topological Galois Theory - Slides 2021, University Toronto
Khovanskii's publications
[Lin 1983] Ferng-Ching Lin: Schanuel's Conjecture Implies Ritt's Conjectures. Chin. J. Math. 11 (1983) (1) 41-50
[Ritt 1948] Ritt, J. F.: Integration in finite terms. Liouville's theory of elementary methods. Columbia University Press, New York, 1948