Here's a proof that your statement is wrong.
First note this: $3^{2n} = 9^n$
If n is even then $9^n \equiv 1 (\mod 5)$, otherwise it's $9^n \equiv -1 (\mod 5)$
Case 1: n is even
We need to prove that:
$$9^n + 2^n + 1 + 1 \equiv 0 (\mod 5)$$, from the upper relations we have
$$2^n \equiv 2 (\mod 5)$$
This one is true only if $n=4k+1$, for $k = 0,1,2,3...$
But this means n is odd which isn't possible because we assume n is even.
Case 2: n is odd
$$9^n + 2^n + 1 + 1 \equiv 0 (\mod 5)$$
$$2^n \equiv 4 (\mod 5)$$
This one is true only for $n=4k+2$ for $k = 0,1,2,3...$
But this is not possible because at the beginning we assum that n is odd.
This means that for any $n = {1,2,3,4,5...}$, this statement is wrong.
Maybe you want a proof that 5 isn't factor of the expression?