Describing the following case as an example for I think the question deserves an answer.
Assume that $a$ has a prime factor $p$ such that it appears with an odd multiplicity in the prime factorization of $a$. It follows that $x^4-a$ is irreducible over $\Bbb{Q}$. Either by Eisenstein or its stronger cousin — the Newton's polygon. Alternatively you can look at this older question and its answers.
In particular, this means that the field extension $K/\Bbb{Q}$, $K=\Bbb{Q}(\root4\of a)$ has degree four. A basis for $K$ as a vector space over $\Bbb{Q}$ consists of the elements $\mathcal{B}=\{1,a^{1/4},a^{1/2},a^{3/4}\}$.
Next we consider the number $s=\root4\of a-\root4\of b$. We assume contrariwise that $s$ is a rational number.
Should this happen it thus follows that $\root4\of b\in K$. Furthermore, raising to the fourth power gives the equation
$$
\begin{aligned}
b&=(\root4\of b)^4=(\root4\of a-s)^4\\
&=a-4a^{3/4}s+6a^{1/2}s^2-4a^{1/4}s^3+s^4\\
&=(a+s^4)-4s^3a^{1/4}+6s^2a^{1/2}-4sa^{3/4},
\end{aligned}
$$
where from last form we can read off the coordinates of $b$ with respect to the basis $\mathcal{B}$.
Because $b\in\Bbb{Q}$, uniqueness of the coordinates implies that all of $-4s$, $6s^2$, $-4s^3$ must vanish. In other words $s=0$, which is the uninteresting case $a=b$.
Galois theory comes to the fore, when we look at more complicated linear combinations of radicals with more than two terms, $\root4\of a+\root4\of b+\root4\of c$ and such. Mostly because it simplifies calculations of the degrees of the relevant field extensions. See the linked threads for more discussion.
Even in the case of a complicated linear combination of square roots Galois theory can be used. See this old answer of mine for an example. I want to emphasize that the use of Galois theory in that answer was a bit of a cutesy show-off. We could have equally well used the natural basis over $\Bbb{Q}$ of the relevant field extension, much the same way we did here.