After looking around a bit I see that this is a standard claim, but I'm wondering if there's any way to argue what I had thought of during a quiz.
I thought to assume that $\mathscr{F}$ was in fact countable, so that there is some bijection $f:\mathscr{F} \rightarrow \mathbb{N}$. If this is the case we can associate every element of the $\sigma$-field to some integer; i.e index them as a sequence $(F_n)_{n \geq 1}$ which contains every element of the $\sigma$-field. But then because $\sigma$-fields are closed under countable unions, we have that $\cup_{n=1}^\infty F_n$ is an element of $\mathscr{F}$ that wasn't in the sequence. Contradiction?
Is there anything that can be done here to salvage this type of argument as it's all I could think of when I encountered this. Also I'd really appreciate if someone could tell me where this idea takes a wrong turn. Thanks in advance for the help!