Notations: $P(XY) := P(X \cap Y)$ and $X' := X^{\small \complement}$.
I read from a comment on MSE that $P(A | B) = P(A)$ and $P(A | B) = P(A | B')$ are equivalent definitions of independence of two events and they both lead to $P(AB) = P(A)P(B)$. The first definition now seems rather natural to me, thanks to @lulu and @Ryan G.
We assume that the probabilities $0 < P(A), P(B) < 1$.
Derivation from the first def.: $P(A|B) = P(A) \iff \frac{P(AB)}{P(B)} = P(A) \iff P(AB) = P(A)P(B)$.
Derivation from the second def.: $P(A|B) = P(A|B') \iff \frac{P(AB)}{P(B)} = \frac{P(AB')}{P(B')}$.
Now if they are equivalent, then $\frac{P(AB')}{P(B')} = P(A) \iff P(A | B') = P(A)$ which is not necessarily the case.
Can anyone please confirm this or tell me what exactly is the statement/assumption that I am missing?