Let $a$ and $b$ be relatively prime positive integers and write the two minimal Bézout's identity pairs,
$\tag 1 (s)\,a + (t)\,b = 1$
$\tag 2 (u)\,a + \;(v)\,b = 1$
where the extended Euclidean algorithm produces one of them
(see this discussion on the structure of solutions).
Set $\quad \; \; x = s - 1$ if $s \gt 0$,
else set $x = u-1$
Set $\quad \; \; y = t - 1$ if $t \gt 0$,
else set $y = v-1$
Let $n = ab - a - b$ be the solution to the Frobenius coin problem for $a$ and $b$.
Conjecture: The numbers $x$ and $y$ derived from the extended Euclidean algorithm satisfy the equation $n + 1 = (a-1)(b-1) = (x)\,a + (y)\,b$
My Work
I noticed this relationship occured while working on this and that (not spelled out in this answer).
Here is another example.
Let $a = 227$ and $b =2011$ and write
$\tag{Z1} (-691)\,227 + (78)\,2011 = 1$
$\tag{Z2} (1320)\,227 + \;(-149)\,2011 = 1$
and $x = 1319$ and $y = 77$.
The statement
$ (1319)\,227 + \;(77)\,2011 = 227\cdot2011 - 227 - 2011 + 1$
is true.
If the conjecture is true one could use the connection to calculate Bézout's coefficients
(in the coprime setting) with new algorithms.
Example: Use an ad-hoc method (algorithm?) to solve for $x$ and $y$ in the equation
$\quad (x)\,227 + \;(y)\,2011 = 227\cdot2011 - 227 - 2011 + 1$
Examining
$\quad 227\cdot2011 - 227 - 2011 + 1 = (2011)\, 227 - 2237$
the problem is reduced to solving
$\quad 227 k \equiv 2237 \pmod{2011}$
That gives $k \equiv 692 \pmod{2011}$ and
$\quad (2011)\, 227 - 2237 =$
$\quad (2011 -692)\, 227 + 692\cdot227 - 2237 =$
$\quad (1319)\, 227 + 154847$
Now use our 'best' algorithm for dividing (exactly) $2011$ into $154847$,
$\quad \large \frac{154847}{2011} = 77$
so
$\quad (1319)\, 227 + 154847 =$
$\quad (1319)\, 227 + (77) \, 2011 $
and we can now easily calculate Bézout's coefficients by solving the linear equations
$\quad (z)\,227 + (78)\,2011 = 1$
and
$\quad (1320)\,227 + (z)\,2011 = 1$