Your matrix has rank $2$, and in particular it can be written in the form
$$
A = xy^T + yx^T,
$$
where $x = (1,0,\dots,0)^T$ and $y = (0,1,\dots,1)^T$. Because $A$ has rank $2$, it has $0$ as an eigenvalue with algebraic multiplicity at least $n-2$; let $\lambda_1,\lambda_2$ denote the two possibly non-zero eigenvalues of $A$.
We can find the eigenvalues of $A$ by noting that the trace of a matrix is the sum of its eigenvalues. In particular, it is clear that $\operatorname{tr}(A) = 0$. Thus, we see that
$$
\lambda_1 + \lambda_2 + 0 + \cdots + 0 = 0 \implies \lambda_1 = -\lambda_2.
$$
On the other hand, we find that
$$
A^2 = (xy^T + yx^T)^2 = xy^Txy^T + xy^Tyx^T + yx^Txy^T + yx^Tyx^T
$$
Conclude that
$$
\lambda_1^2 + \lambda_2^2 = \operatorname{tr}(A^2)
\\= \operatorname{tr}[xy^Txy^T] + \operatorname{tr}[xy^Tyx^T] + \operatorname{tr}[yx^Txy^T] + \operatorname{tr}[yx^Tyx^T]
\\= \operatorname{tr}[y^Txy^Tx] + \operatorname{tr}[x^Txy^Ty] + \operatorname{tr}[y^Tyx^Tx] + \operatorname{tr}[x^Tyx^Ty]
\\= 2(x^Ty)^2 + 2(x^Tx)(y^Ty) = 2(n-1).
$$
Conclude that the non-zero eigenvalues of $A$ are $\pm \sqrt{n-1}$, and the spectral radius is $\sqrt{n-1}$.