The most simple answer will be the phase difference between $\sin x$ and $\cos x$ is $\frac{\pi}{2}$. The point is how trigonometric functions are defined ?
The fact is they are never defined rather interpreted in a logical,pedagogical manner. See if you put $x=\frac{\pi}{2}$ and $y=-x$ in $\sin(x+y)=\sin x \cos y+\cos x \sin y$ then you will get the verification.
But how this formula is derived ?
Simple euclidean geometry. The only defination you need is what is the meaning of sine,cosine in terms of ratio.
Hey wait ! I have used the particular values of sine and cosine. Though some values can be imagined. I will recommend to check out following links.
How would a triangle for sin 90 degree look
How were the sine, cosine and tangent tables originally calculated?