This question shouldn't be read to imply that an uncountable union of open balls/sets is not necessarily open. Indeed, every union of open sets is open, a fact that can easily be proved using the definition of openness implicit in your question (and something that you have likely seen already). This question is giving a finer analysis of open subsets of $\mathbb{R}^n$: Clearly every open subset of $\mathbb{R}^n$ is a union of open balls, but in fact you only need countably many of them to "make" any given open set.
This property is something closely related to the metric structure of $\mathbb{R}^n$ as well as the following topological properties (if these terms are unfamiliar, don't worry about them too much right now; you'll see them if you continue your mathematical studies):
- $\mathbb{R}^n$ is separable (meaning there is a countable dense subset; think of the collection of all points in $\mathbb{R}^n$ with all coordinates rations);
- $\mathbb{R}^n$ is second-countable (meaning that there is a countable collection of open sets such that every open set is a union of sets from this collections; think of the collection open balls of rational radius centred at points with all coordinates rational).
- $\mathbb{R}^n$ is Lindelöf (meaning for every collection of open sets covering $\mathbb{R}^n$ there is a countable subcollection which also covers $\mathbb{R}^n$).
But be warned that not all metric spaces are as nicely behaved as $\mathbb{R}^n$. Indeed, there are metric spaces where not every open set can be expressed as a countable union of open balls. Here are two examples, one of which is somewhat more basic than the other:
- Given any set $X$ the function $d : X \times X \to [ 0 , + \infty )$ defined by $$d ( x , y ) = \begin{cases}0, &\text{if }x = y \\ 1, &\text{if }x \neq y\end{cases}$$defines a metric on $X$ (called the discrete metric). In this space every subset of $X$ is open. If $X$ is uncountable, then any uncountable proper subset $U \subsetneq X$ is an open set which cannot be expressed as the union of countably many open balls.
- A (slightly) more advanced example (which I'm tied to, I guess) would be a (metrizable) hedgehog space of uncountable "spininess".
Again, these examples (especially the latter one) might be somewhat beyond your current level, but they are offered as a warning against thinking that open sets in all metric spaces are countable unions of open balls.