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enter image description here ______________________________________________________________ Conversely, in a different approach using Green's 1st identity, I showed that by choosing v ≡ 1, that the compatibility condition is derived, and so if u is harmonic on Ω, then the integral of the normal derivative over the boundary is equal to zero.

enter image description here ______________________________________________________________ However, for circles/balls lying within the closure of the domain (i.e. intersection with the boundary), do I need to use the mean value principle with Green's theorem to prove that u is a harmonic function in Ω?

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Since every open set can be expresses as a countable union of open balls you don't have to deal with intersection of the closure of an open set $\Omega$ with balls.

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To show that u satisfies the Laplacian, we use Green's 1st identity to obtain the inside-outside theorem equality, setting another arbitrary function, v, contained in the same space as u.

Then, we set v = 1 and obtain an new (simplified) expression of Green's first identity. Hence, for an arbitrary circle B lying in Ω closure, with the compatibility condition = 0, then the integral of the Laplacian = 0. Thus, it follows that the Laplacian = 0 and so the second condition of u being harmonic in Ω is satisfied. enter image description here