This is not true. Consider the $n\times n$ penta-band symmetric Toeplitz matrix
$$
\pmatrix{
2&1&1\\
1&\ddots&\ddots&\ddots\\
1&\ddots&\ddots&\ddots&\ddots\\
&\ddots&\ddots&\ddots&\ddots&1\\
& &\ddots&\ddots&\ddots&1\\
& & &1&1&2}.
$$
It has positive, negative and zero eigenvalues when $n=11$.
An $n\times n$ matrix $A$ is guaranteed to be positive definite if $a_{ij}=\varphi\left(\|x_i-x_j\|^2\right)$ for some completely monotone function $\varphi:[0,\infty)\to\mathbb R$ (i.e. a function such that $(-1)^m\frac{d^m\varphi}{dx^m}\ge0$ on $(0,\infty)$ for every $m\ge0$) and some set of distinct points $\{x_1,\ldots,x_n\}$ in some Euclidean space $\mathbb R^s$. This is known as Schoenberg interpolation theorem, which is a consequence of Bochner's characterisation of positive definite functions. See chapter 15 of A Course in Approximation Theory by Cheney and Light or sec. 2.5 of this book chapter for more details.
In your case, $\varphi(x)=e^{-\sqrt{x}}$ is known to be completely monotone. So, with this function $\varphi$, $A=H-k(0)I$ is positive definite and so is $H$.