It is hard to answer which angle has computable trigonometric functions.
Well we know about famous angles $0,30,45,60,90$ in degrees and their integer multiples.
Then using addition and subtraction of angles, we can calculate exact values of trigonometric functions of $15^\circ$ and $75^\circ$, as well as $22.5^\circ=45^\circ/2$.
We know exact value of trigonometric functions of angles $18, 36,54,72$ in degrees, using a pentagon, or other methods.
For insance
$$\sin(18^\circ)=\frac{\sqrt{5}-1}{4}. $$
Then we can compute exact value of $\sin(3^\circ)=\sin(18^\circ-15^\circ)$.
But note that $3^\circ$ is the least integer angle (in degrees) which its trigonometric functions are expressed in terms of finite radicals. This shows that any angle of the form $(3k)^\circ$ is constructible using compass and straightedge.
Note that, $\sin(1^\circ)$ is computible using the identity
$$\sin(3^\circ)=3\sin(1^\circ)-4\sin^3(1^\circ) $$
but in this case, it is impossible to cancel the imaginary unit $i=\sqrt{-1}$
from inside of radicals.
About trigonometric functions of angles of the form $\frac{2\pi}{N}$, for $N=1,2,3,4,\ldots$.
Among these, for $N\leq20$, the angles
$$\frac{2\pi}{7},\frac{2\pi}{9},\frac{2\pi}{11},\frac{2\pi}{13},\frac{2\pi}{14},\frac{2\pi}{18},\frac{2\pi}{19},\frac{2\pi}{20} $$
have no exact value of trigonometric functions in real radicals but it is astounding that the angle $\frac{2\pi}{17}$ is computible. In fact Gause did it.
$$\cos(\frac{2\pi}{17})=-\frac{1}{16}+\frac{1}{16}\sqrt{17}+\frac{1}{16}\sqrt{\alpha}+\frac{1}{8}\sqrt{17+3\sqrt{17}-\sqrt{\alpha}-2\sqrt{\bar{\alpha}}} $$
where
$$\alpha=34-2\sqrt{17}, $$
$$\bar{\alpha}=34+2\sqrt{17} $$