As we know:
$$e^{i2π} = 1$$
so here's the first way that we can calculate the expression in the title:
$$(e^{i2π})^i = 1^i = 1$$
however, if before we simplify $e^{i2π}$ to $1$ we multiply the powers which we're allowed to do, we get a different result: $$(e^{i2π})^i = e^{ii2π} = e^{-2π} ≈ 0.18 $$
What's the explanation to this?