$\binom{2n}{n}$ is called the central Binomial coefficient. Wikipedia says that the Wallis product can be written in the form of an asymptotic for the central Binomial coefficient. That is, $$\binom{2n}{n} \sim \frac{4^n}{\sqrt{\pi n}}$$
This supposedly has a short proof:
$$
{2n \choose n} =
\frac{4^n}{\pi} \int_{-\pi/2}^{\pi/2} \cos^{2n} x \phantom. dx <
\frac{4^n}{\pi} \int_{-\pi/2}^{\pi/2} e^{-nx^2} dx <
\frac{4^n}{\pi} \int_{-\infty}^{\infty} e^{-nx^2} dx =
\frac{4^n}{\sqrt{\pi n}}.
$$
In the first step, the formula for $\int_{-\pi/2}^{\pi/2} \cos^{2n} x \phantom. dx$ can be proved by using the Beta function.
The third step is clear, and the last step is the well-known Gaussian integral.
So we need only justify the the second step.
There we need the inequality $\cos x \leq e^{-x^2/2}$, that is,
$$
\log \cos x + \frac{x^2}{2} \leq 0,
$$
for $\left|x\right| < \pi/2$, with equality only at $x=0$.
This is true because $\log \cos x +\frac12 x^2$ is an even function that vanishes at $x=0$ and whose second derivative ($-\tan^2 x$) is negative for all nonzero $x \in (-\pi/2, \pi/2)$. Hope it helps.