We can smuggle the core idea of Cayley's theorem from group theory into ring theory and show that $R$ embeds in the ring of endomorphisms of $R$ as an additive group:
$$ \phi : R \to \text{End}(R,+) \quad \text{as} \quad \phi(r) = [s \mapsto rs] \text.$$
Now, $(R, +)$ is cyclic because $n = |R|$ is squarefree, so $\text{End}(R, +) \cong \text{End}(C_n)$, where $C_n$ is the cyclic group of order $n$.
And $\text{End}(C_n) \cong \mathbb{Z}/n\mathbb{Z}$. (If $n \in \mathbb{Z}$, then $g \mapsto n \cdot g = \sum_{i = 1}^n g$ is an endomorphism of any abelian group; in the case of $C_n$, the image of the generator determines the endomorphism.)
So $R$ embeds in $\mathbb{Z}/n\mathbb{Z}$. The embedding must be an isomorphism since the two rings in question are finite.