Recall the Mean Value Theorem that says that for a continuous function on $[a,b]$, and a differentiable function on the interval $(a, b)$, there exists a $c \in (a,b)$ such that
$$\frac{f(b)-f(a)}{b-a} = f^{\prime}(c).$$
Consider working on the interval $[0, x].$ Then, in our case,
$$\frac{e^{-x} - 1}{x} = -e^{-c}$$
for some $c \in (0, x)$. It is clear to see that for any $c$ lying in that interval, $-e^{-c} \geq -1.$ Hence,
$$\frac{e^{-x}-1}{x} \geq -1.$$
The result then follows,
$$e^{-x}-1 \geq -x \implies e^{-x} \geq 1 -x$$
for any $x \geq 0.$