First you need to define $\mathbb{R}$ in your construction!
To define $\mathbb{R}$, one way is to go about defining $\mathbb{N}$, then defining $\mathbb{Z}$, then defining $\mathbb{Q}$ and then finally defining $\mathbb{R}$. Once you have these things set up, proving associativity, commutativity of addition over reals essentially boils down to proving associativity, commutativity of addition over natural numbers.
As said earlier, one goes about first defining natural numbers. For instance, $2$ as a natural number is defined as $2_{\mathbb{N}} = \{\emptyset,\{\emptyset\} \}$. We will use the notation that $e$ is $1_{\mathbb{N}}$ and $S(a)$ be the successor function applied to $a \in \mathbb{N}$.
Then we define addition on natural numbers using the successor function. Addition on natural numbers is defined inductively as
$$a +_{\mathbb{N}} e = S(a)$$
$$a +_{\mathbb{N}} S(k) = S(a+k)$$
You can also define $\times_{\mathbb{N}},<_{\mathbb{N}}$ on natural numbers similarly.
Then one defines integers as an equivalence class (using $+_{\mathbb{N}}$) of ordered pairs of naturals i.e. for instance, $2_{\mathbb{Z}} = \{(n+_{\mathbb{N}}2_{\mathbb{N}},n):n \in \mathbb{N}\}$. You can similarly, extend the notion of addition and multiplication of two integers i.e. you can define $a+_{\mathbb{Z}} b$, $a \times_{\mathbb{Z}}b$, $a <_{\mathbb{Z}} b$. Addition, multiplication and ordering of integers are defined as appropriate operations on these set.
Then one moves on to defining rationals as an equivalence class (using $\times_{\mathbb{Z}}$) of ordered pairs of integers. So $2$ as a rational number, $2_{\mathbb{Q}}$ is an equivalence class of ordered pair $$2_{\mathbb{Q}} = \{(a \times_{\mathbb{Z}} 2_{\mathbb{Z}},a):a \in \mathbb{Z}\backslash\{0\}\}$$ Again define $+_{\mathbb{Q}}, \times_{\mathbb{Q}}$, $a <_{\mathbb{Q}} b$. Addition, multiplication and ordering of rationals are defined as appropriate operations on these set.
Finally, a real number is defined as the left Dedekind cut of rationals. i.e. for instance $2$ as a real number is defined as $$2_{\mathbb{R}} = \{q \in \mathbb{Q}: q <_{\mathbb{Q}} 2_{\mathbb{Q}}\}$$
Addition, multiplication and ordering of reals are defined as appropriate operations on these set.
Once you have these things set up, proving associativity, commutativity of addition over reals essentially boils down to proving associativity, commutativity of addition over natural numbers.
Here are proofs of associativity and commutativity in natural numbers using Peano's axiom.
Associativity of addition: $(a+b) + c = a + (b + c )$
Proof:
Let $\mathbb{S}$ be the set of all numbers $c$, such that $ (a+b) + c = a + (b + c )$, $ \forall a,b \in \mathbb{N}$.
We will prove that $ e$ is in the set and whenever $k \in \mathbb{S}$, we have $S(k) \in \mathbb{S}$. Then by invoking Peano’s axiom (viz, the principle mathematical induction), we get that $\mathbb{S} = \mathbb{N}$ and hence $ (a+b) + c = a + (b + c )$, $ \forall a,b \in \mathbb{N}$.
First Step:
Clearly, $ e \in \mathbb{S}$. This is because of the definition of addition.
$ (a+b)+e = S(a+b)$ and $ a + S(b) = S(a+b)$
Hence $ (a+b)+e = a + S(b) = a+ (b+e)$
Second Step:
Assume that the statement is true for some $ k \in \mathbb{S}$.
Therefore, we have $ (a+b)+k = a+(b+k)$.
Now we need to prove, $ (a+b) + S(k) = a+(b+S(k))$.
By definition of addition, we have $ (a+b)+S(k) = S((a+b) + k)$
By induction hypothesis, we have $ (a+b)+k = a+ (b+k)$
By definition of addition, we have $ b + S(k) = S(b+k)$
By definition of addition, we have $ a+S(b+k) = S(a+(b+k))$
Hence, we get,
$ (a + b) + S(k) = S((a+b) + k) = S(a+ (b+k)) = a + S(b+k) = a+ (b + S(k))$
Hence, we get,
$ (a+b) + S(k) = a + (b+S(k))$
Final Step:
So, we have $ e \in \mathbb{S}$. And whenever, $k \in \mathbb{S}$, we have $S(k) \in \mathbb{S}$.
Hence, by principle of mathematical induction, we have that $\mathbb{S} = \mathbb{N}$
i.e. the associativity of addition, viz,
$$(a+b) + c = a + (b+c)$$
Commutativity of addition: $ m + n = n + m$, $ \forall m,n \in \mathbb{N}$.
Proof:
Let $ \mathbb{S}$ be the set of all numbers $ n$, such that $ m + n = n + m$, $ \forall m \in \mathbb{N}$.
We will prove that $ e$ is in the set $ \mathbb{S}$ and whenever $ k \in \mathbb{S}$, we have $ S(k) \in \mathbb{S}$. Then by invoking Peano's axiom (viz, the Principle Mathematical Induction), we state that $ \mathbb{S}=\mathbb{N}$ and hence $ m + n = n + m$, $ \forall m,n \in \mathbb{N}$.
First Step:
We will prove that $ m + e = e + m$ and hence $ e \in \mathbb{S}$.
The line of thought for the proof is as follows:
Let $ \mathbb{S}_1$ be the set of all numbers $ m$, such that $ m + e = e + m$.
We will prove that $ e$ is in the set $ \mathbb{S}_1$ and whenever $ k \in \mathbb{S}_1$, we have $ S(k) \in \mathbb{S}_1$. Then by invoking Peano's axiom (viz, the Principle Mathematical Induction), we state that $ \mathbb{S}_1=\mathbb{N}$ and hence $ m + e = e + m$, $ \forall m \in \mathbb{N}$.
To prove: $ e \in \mathbb{S}_1$
Clearly, $ e + e = e + e$ (We are adding the same elements on both sides)
Assume that $ k \in \mathbb{S}_1$. So we have $ k + e = e + k$.
Now to prove $ S(k)+ e = e + S(k)$.
By the definition of addition, we have $ e + S(k) = S(e + k)$
By our induction step, we have $ e + k = k + e$.
So we have $ S(e+k) = S(k+e)$
Again by definition of addition, we have $ k + e = S(k)$.
Hence, we get $ e + S(k) = S(S(k))$.
Again by definition of addition, $ p + e = S(p)$, which gives us $ S(k) + e = S(S(k))$.
Hence, we get that $ S(k+e) = S(k) + e$.
So we get,
$ e + S(k) = S(e+k) = S(k+e) = S(S(k)) = S(k) + e$.
Hence, assuming that $ k \in \mathbb{S}_1$, we have $ S(k) \in \mathbb{S}_1$.
Hence, by Principle of Mathematical Induction, we have $ m + e = e + m$, $ \forall m \in \mathbb{N}$.
Second Step:
Assume that $ k \in \mathbb{S}$. We need to prove now that $ S(k) \in \mathbb{S}$.
Since $ k \in \mathbb{S}$, we have $ m + k = k + m$.
To prove: $ m + S(k) = S(k) + m$.
Proof:
By definition of addition, we have $ m + S(k) = S(m+k)$.
By induction hypothesis, we have $ m + k = k + m$. Hence, we get $ S(m+k) = S(k+m)$.
By definition of addition, we have $ k + S(m) = S(k+m)$.
Hence, we get $ m + S(k) = S(m+k) = S(k+m) = k + S(m)$.
We are not done yet, since we want to prove, $ m + S(k) = S(k) + m$.
So we are left to prove $ k + S(m) = S(k) + m$.
$S(k) +m = (k+e) + m = k + (e+m) = k + (m+e) = k + S(m)$.
Hence, we get $ m + S(k) = S(k) + m$.
Final Step:
So, we have $ e \in \mathbb{S}$. And whenever $ n \in \mathbb{S}$, we have $ S(n) \in \mathbb{S}$.
Hence, by Principle of Mathematical Induction, we have the commutativity of addition, viz,
$ m + n = n + m$, $ \forall m,n \in \mathbb{N}$.
We might think that associativity is harder/lengthier to prove than commutativity, since associativity is on three elements while commutativity is on two elements.
On the contrary, if you look at the proof, proving associativity turns out to be easier than commutativity.
Note that the definition of addition, viz $m + S(n) = S(m+n)$, incorporates the associativity $m+(n+e) = (m+n)+e$.
For commutativity however, we are changing the roles of $m$ and $n$, (we are changing the "order") and no wonder it is "harder/lengthier" to prove it.