Inasmuch as the OP requested an approach that is intuitive or geometric, let's proceed accordingly. The ensuing heuristic discussion serves only to supplement the more analytical/rigorous approaches, and can help solidify the understanding of the relationship.
Suppose we have a right triangle formed from the three coordinate points $(0,0)$, $(1,0)$, and $(1,x)$. Note that the tangent of angle $\theta$ between the hypotenuse and the $x$ axis is
$$\tan \theta =x \tag 1$$
We also can see that the tangent of the opposite side angle $\phi$ is
$$\tan \phi = 1/x\tag 2$$
But we know that the sum of the angles $\theta$ and $\phi$ must add to $\pi/2$. We have, therefore, from $(1)$ and $(2)$ that
$$\theta +\phi =\arctan(x)+\arctan(1/x)=\pi/2$$
While in this development, the angles were restricted to be between $0$ and $\pi/2$, we can adapt this same approach show that the relationship is indeed general for $x>0$. And we can also use this approach to show that for $x<0$, $\arctan(x)+\arctan(1/x)=-\pi/2$.