Starting with the famous Basel problem, Euler evaluated the Riemann zeta function for all even positive integers and the result is a compact expression involving Bernoulli numbers. However, the evaluation of the zeta function at odd positive integers (in terms of getting a closed form sum) is still open. There has been some progress in the form of Apery's theorem and other results such as "infinitely many of $\zeta(2n+1)$ are irrational" or "at least one of $\zeta(5),\zeta(7),\zeta(9)$ or $\zeta(11)$ is irrational".
Question(s): Is there a high level understanding for this disparity between even and odd integers? Is it a case of there being a simple expression for $\zeta(3)$ that is out there waiting for an ingenious attack like Euler did with $\zeta(2)$? Or is the belief that such a closed form summation is unlikely? Where do the many many proofs powerful enough to evaluate $\zeta(2n)$ stumble when it comes to evaluating $\zeta(2n+1)$?
Motivation: The Basel problem and Euler's solution are my all-time favorites for the sheer surprise factor and ingenuity of proof (what do $\pi$ and $\frac{sin(x)}{x}$ have to do with $\zeta(2)$??). However, I currently lack the more advanced analytical tools to appreciate the deeper results of this area. I have wondered for a while about the questions above and Internet search hasn't helped much. I would greatly appreciate any answers/references. Thanks.