Now that I've had a chance to read Steven Stadnicki's answer, I see that my answer below is essentially the same, with some added detail.
Since $\frac1{\cos(x)}$ is even, all the odd order terms are $0$. So we will look only at the even order terms. Since
$$
1=\overbrace{\sum_{k=0}^\infty\frac{a_{2k}}{(2k)!}x^{2k}}^{1/\cos(x)}\overbrace{\sum_{j=0}^\infty\frac{(-1)^j}{(2j)!}x^{2j}}^{\cos(x)}\tag{1}
$$
we have that $a_0=1$, and for $k\gt0$,
$$
\begin{align}
0
&=(2k)!\sum_{j=0}^k(-1)^{k-j}\frac{a_{2j}}{(2j)!(2k-2j)!}\\
&=\sum_{j=0}^k(-1)^{k-j}\binom{2k}{2j}a_{2j}\\
&=(-1)^ka_0+a_{2k}+\sum_{j=1}^{k-1}(-1)^{k-j}\binom{2k}{2j}a_{2j}\\
&=\left\{\begin{array}{}
\small\displaystyle(-1)^k+a_{2k}+\sum_{j=1}^{(k-1)/2}(-1)^{k-j}\binom{2k}{2j}(a_{2j}-a_{2k-2j})&\text{if $k$ is odd}\\
\small\displaystyle(-1)^k+a_{2k}+\sum_{j=1}^{(k-2)/2}(-1)^{k-j}\binom{2k}{2j}(a_{2j}+a_{2k-2j})+\binom{2k}{k}a_k&\text{if $k$ is even}
\end{array}\right.\tag{2}
\end{align}
$$
Now we proceed inductively. Assume that for all $j\lt k$, $a_{2j}$ is odd.
If $k$ is odd, then each term of the sum in $(2)$ is even since the difference of two odds is even.
If $k$ is even, then each term of the sum in $(2)$ is even since the sum of two odds is even. For $k\gt0$, $\binom{2k}{k}=2(k-1)\binom{2k-2}{k-1}$ is even.
Therefore, whether $k$ is even or odd, we have that $(-1)^k+a_{2k}$ is even. Thus, $a_{2k}$ is odd.