Questions tagged [stoichiometry]

Stoichiometry refers to the relationship between the amounts of substances of the reactants and the amount of substances of the formed products. This tag should be used for specific questions about chemical reaction equations.

Stoichiometry refers to the relationship between the amounts of substances of the reactants and the amount of substances of the formed products. It is closely related to chemical reaction equations. As the total mass of the reactants has to equal the total mass of the products, it also reflects the law of conservation of mass.

Deriving from this it is possible to calculate the amount of product that will be formed, if the amount of reactants is known, and vice versa. A reaction can be classified as stoichiometric if it follows simple integer ratios, i.e. no excess of reactants or products. $$\ce{NaCl_{(aq)} + AgNO3_{(aq)} -> Na_{(aq)}^{+} + NO3_{(aq)}^{-} + AgCl_{(s)} v}$$

Some reactions are more complicated and involve several reaction paths or mechanisms, but the overall stoichiometry has to be preserved.

The precise IUPAC Definition of Stoichiometry:

The term refers to the relationship between the amounts of substances that react together in a particular chemical reaction, and the amounts of products that are formed. The general stoichiometric equation: $$\ce{a A + b B + \dots -> \dots + y Y + z Z}$$ provides the information that $\ce{a}$ moles of $\ce{A}$ reacts with $\ce{b}$ moles of $\ce{B}$ to produce $\ce{y}$ moles of $\ce{Y}$ and $\ce{z}$ moles of $\ce{Z}$. The stoichiometry of a reaction may be unknown or may be very complex. For example, the thermal decomposition of acetaldehyde yields mainly methane and carbon monoxide, but also a variety of minor products such as ethane, acetone, and diacetyl. The stoichiometric equation $$\ce{CH3CHO -> CH4 + CO}$$ is therefore only an approximate one. Even when the overall stoichiometry of a reaction is well defined, it may be time-dependent in that it varies during the course of a reaction. Thus if a reaction occurs by the mechanism $\ce{A -> X > -> Y}$, and $\ce{X}$ is formed in substantial amounts during the course of the process, the relationship between the amounts of $\ce{A}$, $\ce{X}$ and $\ce{Y}$ will vary with time, and no one stoichiometric equation can represent the reaction at all times.

Further reading:

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Can a chemical reaction have two balanced equations?

I was recently studying Xenon compounds and read this reaction: $$\ce{6XeF4 + 12H2O -> 4Xe + 2XeO3 + 24HF + 3O2}$$ However this reaction can also be written as the following: $$\ce{4XeF4 + 8H2O → 2Xe + 2XeO3 + 16HF + O2}$$ Now both of these are…
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Are matrices a good way to do stoichiometry?

I was never taught in school to use matrices to balance my equation in stoichiometry. But I recently started to review my chemistry and, as I have taken linear algebra, I was suddenly struck by the idea this would be a really efficient way to…
Stan Shunpike
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What is the mathematical meaning of the plus sign (+) in chemical reaction equations?

Reactants and products are connected with plus signs in a chemical reaction equation, e.g. $$\ce{CH4 + 2 O2 -> CO2 + 2 H2O}.$$ Is there a strict mathematical interpretation of what looks like sums before and after the reaction arrow? If so, what do…
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Simplest way to balance any chemical equation

In your opinion, what would be the simplest way to balance any size of the chemical equation? For example here is an equation: $$\ce{C12H26 + O2 -> CO2 + H2O}$$ I saw some ways by putting letters in front of each molecule, but I just don't get…
Pop Flamingo
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What's the difference between reactant, excess reactant and limited reactant in a balanced equation?

In some reactions, the reactant is mentioned as being "excess". For example, "phosphorus pentoxide forms in excess oxygen" or "pentahalides form with excess halogen". But since the balanced equation shows exactly how many moles of a reactant are…
Olga B
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More than one way of balancing a chemical equation

My textbook had this question on balancing chemical reactions Ozone reacts with nitric oxide to give nitrogen dioxide and oxygen gas Here's how I balanced it: $$\ce{O3 + NO -> NO2 + O2}$$ However I realised that the equation is also balanced if I…
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Mathematically balancing chemical equation yields weird results

I found this equation while testing my equation balancer: $$ \ce{a C7H6O3 + b C4H6O3 -> c C9H8O4 + d C2H4O2} $$ Obviously, $a = b = c = d = 1$ is a solution. However, if we were to bring in some maths: $ \begin{cases} 7 a + 4b &= 9c + 2d\\ 6a + 6b…
Jingjie Yang
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Is there a better way balancing reaction equations than systematic trial and error?

I was introduced to the concept of balancing chemical equations in school and I did some practice examples, which were easy and took me about 2 minutes per question. I used the systematic trial and error method and I don't really like it. I'm…
Imagine Dragons
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What is the stochiometric equation of the sucrose and potassium chlorate reaction with sulfuric acid?

I am researching this reaction for my chemistry assessment. Various sources I have dug up state different answers and opinions on what the stoichiometry is and what the products are, sometimes giving no answer at all. In one source, sulfuric acid…
Colin Z
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After completing an experiment, a student finds that the percentage yield exceeded 100%. What could have occurred to the sample to lead to this?

After completing an experiment, a student finds that the percentage yield exceeded 100%. What could have occurred to the sample to lead to this? I am looking for a general answer; nothing too detailed. It happened to me in lab and I am wondering…
Ordinary Owl
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Dimensional Analysis in Chemistry

I was once told on this site that it was incorrect form to use units that specify the chemical being referred to in dimensional analysis. For example: $$150.~\mathrm{g}~~\ce{KNO3} \cdot…
ringo
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What does "a metallic oxide has 40 % oxygen" mean?

Question If a metallic oxide has $40\,\%$ oxygen, find the equivalent weight of the metal. This amounts to finding the atomic weight of the metal and the charge on the cation (in effect identifying the metal itself). I didn't know how to do…
Gerard
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Are chemical equations like a cooking recipe?

Sometimes, balanced chemical equations are compared to cooking recipes. Here is one example: Imagine if you were baking chocolate chip cookies and measured out your ingredients incorrectly. What if you added 2 tablespoons of flour instead of two…
Karsten
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Percent of silver by mass in an unknown sample

Question If all of the silver in a $7.563~\mathrm{g}$ sample of a mineral, which was dissolved by using nitric acid, is precipitated as silver thiocyanate ($\ce{AgSCN}$) by using $82.46~\mathrm{mL}$ of a $0.2500~\mathrm{M}$ potassium thiocyanate…
Noah Caldwell
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Question about null space balancing method

I'm trying to use the null space method to balance the following equation: . I obtained the following composition matrix: $$\begin{bmatrix} 3 & 8 & 1 & 12 & 4 & 2 \\ 1 & 0 & 0 & 1 & 0 & 0 \\ 4 & 4 & 3 & 40 & 3 & 1 \\ 0 & 2 & 1 & 3 & 1 & 0 \\ 0 &…
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