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I learned that square brackets ex: $[\ce{H2O}]$ can be used to denote the concentration of water molecules in a fluid. The notation used much in equilibrium problems and such.

However, sometimes I have seen curly brackets {} being used in similar scenarios, but I never really understood the difference. When are curly brackets used and what do they mean?

I found this example from an exam where the problem is to see if a solution of $\ce{Ca(OH)_2}$ in water is concentrated enough to result in precipitation.

Following is what how they solve it in the example:

  1. Solubility constant for $\ce{Ca(OH)_2}$ is given as $K_\mathrm{s} = \{\ce{Ca^{2+}}\}\{\ce{OH^-}\}^2$ (100% saturation point I think)
  2. $Q = \{\ce{Ca^{2+}}\}\{\ce{OH^-}\}^2 \approx [\ce{Ca^{2+}}][\ce{OH^-}]^2$ (actual saturation I think)

Where $Q$ is the actual saturation of the solution. And the answer is that no precipitation occurs since $Q < K_\mathrm{s}$ in this specific example.

So they seem to suggest that {} is something different than the concentration [] and that it can be approximated to the concentration.

Tyberius
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dekuShrub
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  • Hmm, the place I've seen curly brackets as you describe is for inorganic crystalline substances - see this link for an explanation. That said, they are used to denote the constitution of structural units and not used to enclose chemical species, so the use case I present might not be relevant to yours. – Todd Minehardt May 30 '16 at 17:57
  • It doesn't seem to have anything with crystalline substances to do. I found an example where they use the denotation which I edited in. – dekuShrub May 30 '16 at 18:51
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    In that context I would guess it is referring to the activity, although I don't think that is a standard notation for it, usually one would write $a_{\ce{Ca^2+}}a_{\ce{OH-}}^2$ – orthocresol May 30 '16 at 18:59
  • Curly braces are often also used to denote encounter pairs, or molecules held together in solvent cages, but that's obviously not what you're talking about – orthocresol May 30 '16 at 19:01

1 Answers1

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The curly brackets denote "activity of" the species therein.

See the Wikipedia section: Basic definitions and properties of Equilibrium constant

Gaurang Tandon
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DavePhD
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