As @narip already mentioned in the comments, the statevector simulator of the IQX (your top picture) shows that one state has 100% measure probability since you added measurements and thus the state collapses. You should only add measurements for shot-based readouts, not if you do statevector simulations.
Regarding your question about the Hadamard gate: I think there are actually some Hadamards missing! Based on your circuit I assume the oracle/boolean function you want to implement is $f(x_1, x_2) = x_1 \text{ and } x_2$. The Toffoli gate with surrounding X gates you implemented indeed flips a target qubit if both qubit 1 and 2 are 0. But keep in mind that Grover's oracle must do phaseflip and not a bitflip! To convert your oracle you should add two Hadamards around the target qubit, to be
┌───┐ ┌───┐
x_1: ┤ X ├──■──┤ X ├
├───┤ │ ├───┤
x_2: ┤ X ├──■──┤ X ├
├───┤┌─┴─┐├───┤
target: ┤ H ├┤ X ├┤ H ├
└───┘└───┘└───┘
And on top of that, you should have an initial layer of Hadamards, to initialize in an equal superposition. In total your circuit would be something like
┌───┐┌───┐ ┌───┐┌───┐┌───┐ ┌───┐┌───┐
x_1: ┤ H ├┤ X ├──■──┤ X ├┤ H ├┤ X ├──■──┤ X ├┤ H ├────
├───┤├───┤ │ ├───┤├───┤├───┤ │ ├───┤├───┤
x_2: ┤ H ├┤ X ├──■──┤ X ├┤ H ├┤ X ├──■──┤ X ├┤ H ├────
├───┤├───┤┌─┴─┐├───┤└───┘└───┘ └───┘└───┘
target: ┤ H ├┤ H ├┤ X ├┤ H ├─────────────────────────────
└───┘└───┘└───┘└───┘