In a lecture on Baire's Theorem (for complete metric spaces), I gave, for a rather advanced undergraduate class in Real Analysis (covering the theory of metric spaces and elements of general topology), I realised that all the applications I provided were either straight-forward or could be proved using more elementary tools. For example:
a. $\mathbb Q$ is not complete.
b. $\mathbb R$ is uncountable. (Otherwise, if $\mathbb R=\{x_n\}_{n\in\mathbb N}$, then $\bigcap_{n\in\mathbb N} (\mathbb R\setminus\{x_n\})$ would be dense and empty.)
c. A complete metric, with the property that every point is an accumulation point, is uncountable.
Could you suggest more interesting applications? They do not have to be too easy to prove.