As I mentioned in my comment, you can't really answer this question without knowing the distribution of the results, not just the mean and standard deviation. Let's say your values are distributed according to the binomial distribution (which is the discrete analog of the normal distribution) for a 4-trial binary experiment. The probability of the result being $k + 1$ is
$$P(k + 1) = \binom{4}{k}p^k(1-p)^{4-k}$$
But you don't have the value of $p$ directly; instead, you have the mean $\mu + 1 = 4p$ and standard deviation $\sigma + 1 = \sqrt{4p(1-p)}$. (The +1's come up because your data start at 1 rather than 0.) So you will need to solve for $p$ as $p = \frac{\mu + 1}{4}$. You should check that plugging this into the standard deviation formula $\sqrt{4p(1-p)}$ gives you something close to the actual standard deviation of your data, otherwise the binomial distribution is not an accurate representation of your data.
Once you have satisfied yourself that the binomial distribution is roughly accurate and that you have properly calculated $p$, you can compute the probability of getting a 4 or a 5 as
$$P(4) + P(5) = 4p^3(1-p) + p^4$$
This will give you a good approximation to the fraction of 4s and 5s in your data set; just multiply by $n$ to get the number of 4s and 5s. How good the approximation is depends on how well your data fit the binomial distribution, and you can use the matching of the standard deviations as an indicator for that.
I don't know of any practically useful way to get the number of 4s and 5s more exactly. You could write out the equations for the mean and standard deviation,
$$\begin{align}\frac{1}{n}\sum_{i=1}^n k_i &= \mu & \frac{1}{n}\sum_{i=1}^n (k_i - \mu)^2 &= \sigma^2\end{align}$$
and try to plug in numbers for the $k_i$ to see if you can come up with a set that matches your $\mu$ and $\sigma$ exactly, but that's just trial and error and it will likely not have a unique solution anyway.
Perhaps you could supply a bit more context? Where did this problem come from? How do you know the data are well approximated by a normal distribution? What are the parameters of that distribution?
– Andrew Christianson Dec 12 '11 at 00:44