Edit: TonyK's comment (amplifying Antonio Vargas') answers the question. The following is a sketch of an alternative argument.
$\psi(x) = \sum_{p^k \leq x }\log p \sim x$ [PNT]. Using your (or the comments) definition of $\Pi(x)$ if we have, for example, $x = 20,$
$$ \psi(x) = \log 2+ \log 2^2 +\log 2^3 +\log 2^4 +\log 3 + \log 3^2 + \log 5+ ... + ~\log 19.$$
Rewrite as:
$(\log 2\cdot 2^2\cdot 2^3\cdot2^4) + (\log 3\cdot 3^2) +...+~ (\log 19) = (1+2+3+4) \log 2 + (1+2)\log 3 +...,$ etc.
Notice that the cardinality of $p^k$ is the highest power in each of the terms on the left side of the equality above, or the highest term in the coefficients of the logs, $(1+2+3+4),~ (1+2),$ etc. For 20,
$$ \frac{\Pi(20)}{\psi(20)} = \frac{4 + 2+~ ...~ + 1}{10 \log 2 + 3\log 3+~...~+ \log 19} $$
and as x grows the coefficients in the denominator are $k(k+1)/2$ while the corresponding terms in the numerator are k. In the example above, $10 = (4\cdot 5) /2$ and $3 = (2\cdot 3)/2.$ Since $\log n > 1$ for $n \geq 3$ the terms in the denominator are growing a lot faster than those in the numerator so
$$\frac{\Pi(x)}{x} \sim \frac{\Pi(x)}{\psi(x)} \sim 0. $$
Using Mathematica and the formula suggested in the comments above I calculated $\frac{\Pi(x)}{x}$ for x = 10, 100, 1000, 10000, 100000. I get:
0.7, 0.35, 0.193, 0.128, 0.097, so the limit appears to be zero.