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Let $A$ be the Cantor set and $B = \pi\, (-A \cup A)$.

Is B a perfect set with no rational numbers?

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As Andres Caicedo pointed out, $B$ contains $0$.

It is reasonable to ask whether $B$ contains a nonzero rational number. This is equivalent to asking whether $A$ contains a rational multiple of $\pi$ (other than $0$).

If the answer is affirmative, then the base $3$ expansion of $\pi$ has a (complicated) infinite pattern in its digits. It is generally believed that the digits of $\pi$, in any number base, do not exhibit any infinite pattern. However, for all we know at present, the base 3 expansion of $\pi$ could have finitely many $1$s. (See Distribution of the digits of Pi and links there.) So, the answer to your question (with excluded $0$) is: nobody knows.