From the definition of the characteristic polynomial as $\det(I_nX-A)$, it is clear that its coefficient of $X^{n-1}$ is $\def\tr\{\operatorname{tr}}-\tr A$: to get a contribution of degree $n-1$ in $X$ in the Leibniz formula for the determinant you need to pick up those $n-1$ factors $X$ on the diagonal, and the remaining factor will be a $-A_{i,i}$ on the diagonal in the same entry as the one factor$~X$ that was not chosen (this is summed over all$~i$). Also it is clear that the product $(X-\lambda_1)^{r_1}\ldots(X-\lambda_k)^{r_k}$ has a term $(-r_1\lambda_1-\cdots-r_k\lambda_k)X^{n-1}$.
As for the part about traces of $A^k$, these give the sums over the $k$-th powers of the eigenvalues $\lambda_i$, each $k$-th power $\lambda_i^k$ being taken with the multiplicity $r_i$ of its eigenvalue; call this the $k$-th power sum $p_k$ of the eigenvalues. Now if the power sums $p_1,\ldots,p_n$ are all zero, then it follows in characteristic$~0$ from Newton's identities that the elementary symmetric polynomials $e_1,\ldots,e_n$ of the (multiset of) eigenvalues are also all$~0$, and since these are up to a sign the non-leading coefficients of the characteristic polynomial, that polynomial is $X^n$. In particular the constant term of the characteristic polynomial, which is $\det(-A)$, is zero (if $n>0$), so $A$ is singular. In fact one can say more, namely that $A$ is nilpotent.