A simple example of an incomplete measure is the following:
Let $\nu$, $\lambda$ each be the Lebesgue Measure on $\mathbb{R}$, and for a rectangle $I_1\times I_2 \subset \mathbb{R}\times\mathbb{R}$, define
$\mu\, : \, \mathcal{P}(\mathbb{R}\times\mathbb{R}) \to \mathbb{R}_{>0}$ by
$\mu(I_1\times I_2) = \nu(A)\lambda(B)$
Now, consider the rectangle $Q = [0,1] \times [0,1]$, and the subset
$\Omega = \{(x,y) \in Q \, | \, x=0,\, 0\leq y\leq 1 \} \subset Q$.
Then surely, $\mu(\Omega) = 0$. Now, there exists a nonmeasurable subset $A\subset [0,1]$ (for instance, the Vitali set). Let $A_1 = \{0\} \times A \subset \Omega \subset Q$. Then (denoting by $\mu^*$ the completion of $\mu$), we have that $\mu^*(A_1) = 0$, but $A_1$ is not $\mu$-measurable.
While any subset of a zero measure set can be expressed as the complement of an infinite union, this doesn't help to classify, complete, or otherwise resolve the issue we have above with the set $A_1$, because the infinite union need not be countable (take, for instance, the Cantor Set). Measure is countably additive, and the expression of a subset as a complement of an infinite union does not guarantee that the set has measure $0$, so I'm not sure what this gives you, in general.
One of the things that we must resolve in measure theory is eliminating the possibility of nonmeasurable subsets of sets of measure zero, which we accomplish by completing the measure. We can't simply ignore the existence of these sets by saying they don't exist (surely I have given an example above). So we have to address these in a way that would remain logically consistent with the monotonicity of measure, and other properties of measure we have. Namely, we would want the subset of any null set to be measurable (and null), which is another way of saying the measure should be complete.
We don't necessarily need to be overly concerned about nonmeasurable subsets of finite measure sets, because even when we complete the measure, we may still have nonmeasurable sets. Lebesgue measure on $\mathbb{R}$ is complete, but the Vitali set $A$ is nonmeasurable, and can be scaled down or up to be a subset of a set of arbitrary measure, so we can't guarantee this.
What we can do, in general, is pass to the completion of our $\sigma$-Algebra (guaranteeing all subsets of null sets are measurable), extending the measure to be complete, in which case we need not concern ourselves too much with incomplete measures, but as the previous answer noted, this may not be feasible, or may make the $\sigma$-Algebra far more complicated than the original $\sigma$-Algebra you were working with.