Let $G_1, G_2$ be two groups that act on a set $S$ on the left, such that for all $g \in G_1$ there's $g' \in G_2$ such that $g\cdot s = g'\cdot s$ for all $s \in S$.
Define $h : G_1 \to G_2$, $h(g) = g'$ as defined above. Then $h(ab) = (ab)'$. Well $(ab)\cdot s = (ab)'\cdot s \ \forall s \implies \text{ it equals } a(b\cdot s) = a'(b'\cdot s)$. But I can't conclude that $(ab)' = a'b'$.
How are the two groups related?
Thanks @ThomasAndrews. "If the group actions are faithful then $G_1 \approx G_2$."
Let $h$ be well-defined by choosing any such $g'$ for each $g \in G_1$. From the above, as $(ab)' \cdot s = a'(b' \cdot s)$, we have that $b'^{-1} a'^{-1} (ab)' = 1$, so that equality follows. That means if $G_2 \times S \to S$ is faithful then $h$ is a homom. $h$ is injective as $g'\cdot s = h' \cdot s \ \forall s$, then by faithfullness of $G_2$ again $g' = h'$.
Intuitively, if we have the similar requirement and a map $h' : G_2 \to G_1$, then $h$ becomes an isomorphism.