Being finite and separable the extension $K/k$ is necessarily simple, so $K=k(\alpha)$ for some element $\alpha\in K$. Let $p(x)$ be the minimal polynomial of $\alpha$. The field $L$ is then the splitting field of $\alpha$, so over $L$ we have a factorization
$$
p(x)=(x-\alpha_1)(x-\alpha_2)(a-\alpha_3)(x-\alpha_4)
$$
with $\alpha=\alpha_1$.
The Galois group $G=Gal(L/k)$ can then be any transitive subgroup of the group of permutations of the set $\{\alpha_1,\alpha_2,\alpha_3,\alpha_4\}$. So $G\le S_4$, it must be transitive, and its order must be a multiple of 4. In addition to the ones you listed the dihedral group of 8 elements and the groups $A_4$ and $S_4$ are all possibilities.
Edit: To answer the added question. If $L/k$ contains a quadratic extension $F/k$, then Galois correspondence tells us that $G$ must have a subgroup $H$ of index two such that $F=Inv(H)$ (or $H=Gal(L/F)$). This rules out the possibility that $G\simeq A_4$. The other possibilities remain.