Short version: can we prove that $$\sum_{k=0}^n (-1)^k \binom{n}{k}^2 \frac{k!}{n^{2k}} \to \frac1e$$ as $n \to \infty$?
Long version: First, consider $$a_n = \sum_{k=0}^n \frac{(-1)^k}{k!}$$ It is well-known that $a_n \to \dfrac1e$ as $n \to \infty$; indeed $a_n = \dfrac{!n}{n!}$ is the truncation to the first $n$ terms of the power series for $e^x$, evaluated at $x = -1$ (where $!n$ denotes the subfactorial; it is also equal to the number of derangements on $n$ elements). There is also a simple expression for the generating function $A(z) = \sum_{n=0}^{\infty} a_n z^n$, which is $A(z) = \dfrac{e^{-z}}{1-z}$. (See Exponential Generating Functions For Derangements.)
Next, consider $$b_n = \sum_{k=0}^n \frac{n^{\underline k}}{n^k} \frac{(-1)^k}{k!}$$ where $n^{\underline k} = \binom{n}{k}k!$ denotes a falling factorial, so the extra factor $\frac{n^{\underline k}}{n^k}$ is $\frac{n(n-1)\cdots(n-k+1)}{n(n)\cdots(n)} = 1\cdot\left(1 - \frac1n\right)\cdot\left(1 - \frac2n\right)\cdots\left(1 - \frac{k-1}n\right)$ which for large $n$ (and fixed $k$) is close to $1$. I don't know if $b_n$ has a simple form for its generating function too, but it is easy to see that $b_n \to \dfrac1e$ as well; indeed by the binomial theorem we have $b_n = \sum_{k=0}^n \binom{n}{k} (\frac{-1}{n})^k = \left(1 - \frac1n \right)^n$ which is well-known to converge to $\frac1e$ (indeed such a limit is sometimes taken to be the definition of $e^x$).
Finally, consider $$c_n = \sum_{k=0}^n \frac{n^{\underline k}}{n^k} \frac{n^{\underline k}}{n^k} \frac{(-1)^k}{k!}$$
This is the same transformation going from $b_n$ to $c_n$ as from $a_n$ to $b_n$. But can we prove that $c_n \to \frac1e$ too? (And can we write down its generating function compactly, perchance?) More generally, what techniques exist that help in proving something about $\sum t_n s_n$, given $\sum s_n$?
This question arose from an attempt to answer this question, where I arrived at the expression $c_n$ above (there I called it $P_{n, n, 0}$; next I'll try to understand $P_{m, w, k}$).
[Note: I'm tagging this special-functions too, as I understand $c_n$ has something to do with hypergeometric functions / Bessel functions / something like that.]