If we have a function $f(s)$ with this form:
$$ f(s) = \sum_{i=0}^{\infty} p_i s^i $$
We also know that:
$$ f(1) = 1 $$
and
$$ p_i \ge 0 \quad \text {for all $ i \ge 0$} $$
Assume we can calculate $f(s)$ for any $s$, is it possible that with all the info we know, we would be able to get $p_n$ for any n?
(Actually $p_i$ is the probability that $[Z=i]$ where Z is a random variable.)