I think you can see that
$0< \frac{n}{m} < 1$
Now you can't say "as n approaches 0" because $n \in \mathbb{Z}_+$.. but you can say that if $n=1$, then $\frac{n}{m} = \frac{1}{m}< \epsilon$ for every $\epsilon > 0$ (just take $m > \frac{1}{\epsilon}$)
So you will never reach $0$, but for every number $\epsilon$ as close to zero as one wants, then we can find $n, m$ such that $\frac{n}{m} < \epsilon$. This implies $\inf(A) = 0$.
In fact, if you defined $\inf(A)$ in the standard way, (as the greatest element of A that is less than or equal to all elements), then one can say: "Suppose $\inf(A) = \epsilon \neq 0$. This means $\epsilon \le x, \forall x \in A$, but we have shown this is not the case.
So $\epsilon \le 0$.
We have already shown that if $\epsilon \le 0$, then it's true $\epsilon \le x, \forall x \in A$.
What is then the greates $\epsilon$ with such a property? $0$ ! So $\inf(A) = 0$
Can you complete the proof and show that $\sup(A)= 1$?
EDIT
I see maybe you need a clearer explanation.
We want to prove $\inf(A) = 0$
This means that we want to prove that $0 \le x \ \forall x \in A$, and that $0$ is the greatest number with such property.
We're gonna do it with the so called Proof by contradiction (http://en.wikipedia.org/wiki/Proof_by_contradiction)
Let's suppose $\inf(A) = b > 0$. ($b < 1$)
Then $b \le \frac{n}{m} \forall \ n, m$ (1)
For $n = 1$, $m = \frac{2}{b}$ (note that this way $\frac{n}{m} \in A$) we have $b \le \frac{b}{2}$ which is false.
So $b$ cannot be $> 0$ and has to be $b = 0$.
Basically you start with the definition of $\inf(A)$ and try to find a contradiction.