Here's one quick way to see this:
Suppose that $\exp(r_1 t)$ and $\exp(r_2 t)$ are not linearly independent. Then there exist scalars $a, b$ such that
$a \exp(r_1 t) + b \exp(r_2 t) = 0, \tag{1}$
and if we set $t = 0$ we obtain
$a + b = 0. \tag{2}$
Now if we differentiate (1) with respect to $t$ we obtain
$ar_1 \exp(r_1 t) + br_2 \exp(r_2 t) = 0, \tag{3}$
and again taking $t = 0$ we find
$ar_1 + br_2 = 0. \tag{4}$
But if $r_1 \ne r_2$ the only solution to the linear system in $a, b$, given by (2), (4) is
$a = b = 0$. You can see this by writing the equations as a matrix-vector system
$\begin{bmatrix} 1 & 1 \\ r_1 & r_2 \end{bmatrix} \begin{pmatrix} a \\ b \end{pmatrix} = 0, \tag{5}$
and noting that
$\det(\begin{bmatrix} 1 & 1 \\ r_1 & r_2 \end{bmatrix}) = r_2 - r_1 \ne 0 \tag{6}$
since $r_1 \ne r_2$. Since $a = b = 0$, $\exp(r_1 t)$ and $\exp(r_2 t)$ are linerly independent.
Hope this helps. Cheerio,
and as always,
Fiat Lux!!!