Is there a continuous function on R such that $f(f(x))=e^{-x}$? I have tried to take derivative of the two sides,but I can't get anything I want.what can I do?
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No. Hint: An injective continuous function is monotonic and for any monotonic $f(x)$ the function $f(f(x))$ should be increasing.

njguliyev
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This is only if f required to be real-valued. If it is allowed being complex-valued (but continuous and defined on R), it can exist. – Anixx Nov 19 '14 at 16:49