Consider the graph of $y=|x|$ from $-1<x<1$. Equip it with a single chart, the projection onto the $x$-axis. Is it now a smooth manifold? It seems like it shouldn't be smooth, but perhaps with only one chart, any manifold is smooth (because it trivially satisfies the compatibility condition)?
What chart could we put on there that would not be smoothly compatible with this first one?