It may be rather tedious and I will have to delve into deeper, but I have a little something. We probably already know this one. The thing is, the first one results in yet another Euler sum. But, I think we can get it without contours. It may require some work, though.
$$ \sum_{n=1}^\infty\frac{H_n^{(2)}}{n^{4}} = \sum_{n=1}^\infty\sum_{k=1}^n \frac 1 {k^4} = \sum_{n=1}^\infty\frac 1{n^2} \sum_{k=n}^\infty\frac 1{k^4}\ . $$ This result:
$$ \sum_{n=1}^{\infty}\frac{H_n^{(2)}}{n^4} = \zeta(2)\zeta(4)+\zeta(6) -\sum_{n=1}^{\infty}\frac{H_n^{(4)}}{n^2} $$ where that sum on the end is equal to $$ \sum_{n=1}^{\infty}\frac{H_n^{(4)}}{n^2} =\frac{37}{12}\zeta(6)-\zeta^{2}(3)\ . $$ Which matches up if we change it all to $\zeta(6)$
i.e. $\displaystyle \zeta(4)\zeta(2)=\frac{7}{4}\zeta(6)$
and $$ \sum_{n=1}^{\infty}\frac{H_n^{(2)}}{n^4} =\zeta(2)\zeta(4) + \int_0^1\frac{\log(x)\operatorname{Li}_4(x)}{1-x}\; dx $$
My main question is how to evaluate the last integral. Any better ways to evaluate the main Euler sum are welcome.