I will try to answer what I guess you question is. Namely I will show that if $0 \in U \subseteq \mathbb R^k$ is an open, connected subset and $U \setminus \{0\}$ is not connected, then necessarily $k = 1$.
The first thing to note is that the open, punctured ball $B_\varepsilon(0) \setminus \{0\}\subseteq \mathbb R^k$ is connected for any $\varepsilon >0$ and $k > 1$, because it is even path connected.
Let $0 \subseteq U \subseteq \mathbb R^k$ be open and connected for some $k>1$. Choose some $\varepsilon > 0$, such that $B_\varepsilon(0) \subseteq U$. Now suppose that $U\setminus \{0\}$ was not connected. Then by definition, there exist two non-empty disjoint open sets $V_1, V_2$ such that $U \setminus \{0\} \subseteq V_1 \cup V_2$. If $(B_\varepsilon(0)\setminus \{0\}) \cap V_i$ are both non-empty, then we have written the connected set $B_\varepsilon(0)\setminus \{0\}$ as the union of two non-empty connected sets, which is a contradiction. So, w.l.o.g suppose that $B_\varepsilon(0) \subseteq V_1$. Now $W_1 := B_\varepsilon(0) \cup V_1$ and $W_2 := V_2$ are both open, disjoint (one needs to make sure that $0\notin V_2$, why is that so?) and cover $U$. But again, that contradicts the connectedness of $U$.
So $U \setminus \{0\}$ has to be connected as well, which establishes the claim.
Maybe you want to show that if $0 \in U \subseteq \mathbb R^k$ is open, connected such that $U \setminus {0}$ is no longer connected implies $k=1$?
In that case, you may just work with the definition. You can show that if $k > 1$, then if you have a path in $U$ connecting two points, you can deform that path to miss $0$, and by doing so, show that $U \setminus {0}$ is still (path-)connected for $k>1$.
– Sven-Ole Behrend Jan 15 '24 at 12:44