For the first one OP proposes
$$E_n = -\sqrt{2} \;\sum_{k=0}^n {n\brace k}
\frac{k!}{\sqrt{2}^k} \cos(3\pi (k+1)/4).$$
which is
$$E_n = -\sqrt{2} \; \Re \sum_{k=0}^n {n\brace k}
\frac{k!}{\sqrt{2}^k} \exp(3\pi i (k+1)/4).$$
Using the Stirling set number EGF this becomes
$$- \Re \left[ n! [z^n] \; (-1+i)
\sum_{k=0}^n (\exp(z)-1)^k \frac{1}{\sqrt{2}^k}
\exp(3\pi i k/4) \right].$$
We may extend the inner sum to infinity due to the coefficient extractor
and the fact that $\exp(z)-1 = z + \cdots$, getting
$$\Re \left[ n! [z^n] \; (1-i)
\frac{1}{1-\exp(3\pi i/4)(\exp(z)-1)/\sqrt{2}} \right]
= \Re \; n! [z^n] f(z).$$
We have that $f(z)$ simplifies to
$$\frac{2(1-i)}{1+i+\exp(z)(1-i)} = \frac{2}{i+\exp(z)}.$$
For the real part we need the EGF of the conjugates. Using
Mittag-Leffler we start with (poles of $f(z)$ are simple with
residue $2i$)
$$g(z) = \sum_k \frac{2i}{z-(-\pi i/2 + 2\pi i k)}
= \sum_k \frac{i(2z+\pi i)}{(z+\pi i/2)^2 - (2\pi i k)^2}$$
(the latter is convergent) and we can evaluate the sum through the
residues in $w$ using the function
$$h(z,w) = - \frac{1}{w+(z+\pi i/2)} \frac{1}{w-(z+\pi i/2)}
i(2z+\pi i) \cot(-iw/2) \frac{1}{2i}.$$
We use the fact that the residues in $w$ of $h(z,w)$ sum to zero and the
residue at infinity is zero so that the residue at the two simple
poles $w=\pm(z+ \pi i/2)$ produces for $g(z)$ (flip sign due to
residue sum)
$$g(z) =
- \frac{1}{2} \cot(-i(-(z+\pi i/2))/2)
+ \frac{1}{2} \cot(-i(+(z+\pi i/2))/2)
\\ = - \frac{1}{2} \cot(iz/2-\pi/4)
+ \frac{1}{2} \cot(-iz/2+\pi/4)
\\ = \cot(-iz/2+\pi/4).$$
We get for $g(z)$
$$\frac{\cos(-iz/2+\pi/4)}{\sin(-iz/2+\pi/4)}
\\ = i \frac{\exp(z/2)\exp(\pi i/4)+\exp(-z/2)\exp(-\pi i/4)}
{\exp(z/2)\exp(\pi i/4)-\exp(-z/2)\exp(-\pi i/4)}
\\ = i \frac{\exp(z)\exp(\pi i/4)+\exp(-\pi i/4)}
{\exp(z)\exp(\pi i/4)-\exp(-\pi i/4)}
= i\frac{\exp(z)i+1}{\exp(z)i-1}
= \frac{\exp(z)i+1}{i+\exp(z)}.$$
The difference between $f(z)$ and $g(z)$ is exactly $-i$ and we
finally have
$$f(z) = -i + \sum_k \frac{2i}{z-(-\pi i/2 + 2\pi i k)}.$$
We seek the generating function of the conjugates which can now be
obtained by inspection and is seen to be (expand terms into a series
about zero)
$$f_C(z) = i + \sum_k \frac{-2i}{z-(\pi i/2 - 2\pi i k)}
= i - \sum_k \frac{2i}{z-(\pi i/2 - 2\pi i k)}.$$
Here we have applied conjugation to
$$\frac{C}{z-\rho} =
-\frac{C}{\rho} \frac{1}{1-z/\rho}
= -\frac{C}{\rho} \sum_{q\ge 0} \frac{z^q}{\rho^q}.$$
We claim this is $-f(z-\pi i)$ and check
$$- f(z-\pi i) = i - \sum_k \frac{2i}{z-\pi i -(-\pi i/2 + 2\pi i k)}
= i - \sum_k \frac{2i}{z-(\pi i/2 + 2\pi i k)}.$$
We are iterating over $k$ in two possible directions.
Returning to the original problem we have that our answer is given by
$$\Re \; n! [z^n] f(z) = \frac{1}{2} n! [z^n] (f(z)+f_C(z)).$$
Using the expression for $f_C(z)$ in terms of $f(z)$ this becomes
$$\frac{1}{i+\exp(z)} - \frac{1}{i+\exp(z-\pi i)}
= \frac{1}{i+\exp(z)} - \frac{1}{i-\exp(z)}
\\ = \frac{i-\exp(z)-i-\exp(z)}{(-1)-\exp(2z)}
= \frac{2\exp(z)}{\exp(2z)+1} = \frac{1}{\cosh(z)}.$$
We have obtained the EGF of the Euler numbers and may conclude.
Remark. The computation of the residue at infinity being zero
may be seen at the following MSE
link.