Will this work?:
Let $\phi(x) \in K[x]$ be the minimal polynomial of $u$. Consider $f(u) \in K[u]$ where
$f(x) \in K[x]$. I claim we can take $\deg f < \deg \phi$ without loss of generality. Why? If $\deg f \ge \deg \phi$, we can use the division algorithm in $K[x]$ to write $f(x) = \phi(x) q(x) + r_f(x)$, where $\deg r_f < \deg \phi$. Then $f(u) = \phi(u) q(u) + r_f(u)$, whence, since $\phi(u) = 0$, $f(u) = r_f(u)$. I claim that $\phi(x)$ must be irreducible in $K[x]$. Why? If $\phi(x) = \alpha(x) \beta(x)$ in $K[x]$, and neither $\alpha(x)$ nor $\beta(x)$ is constant, i.e. of degree $0$, then we would have $\alpha(u) \beta(u) = \phi(u) = 0$, whence either $\alpha(u) = 0$ or $\beta(u) = 0$. But $0 < \deg \alpha < \deg \phi$, $0 < \deg \beta < \deg \phi$, so this contradicts the minimality of $\phi(x)$. Since $\phi(x)$ is irreducible, it is prime in $K[x]$, a principal ideal domain. Since $\phi(x)$ is prime, we must have $\gcd(\phi(x), r_f(x)) = 1$, since we cannot have $\phi(x) \vert r_f(x)$ by virtue of the fact that $\deg r_f < \deg \phi$, whence there exist $g(x), h(x) \in K[x]$ such that $r_f(x)g(x) + \phi(x)h(x) = 1$. But then $r_f(u)g(u) = 1$, since $\phi(u) = 0$. QED.
P.S. After the above breakdown, I must point out that the evaluation homomorphism
$\theta:K[x] \to K[u]$ has kernel precisely $(\phi(x))$ in $K[x]$, whence $K[u]$ is isomorphic to $K[x]/(\phi(x))$, a field since $\phi(x)$ is prime etc. etc. etc. Less typing! ;)