First, that expression is not an integer, but very close to an integer $640320$. In fact, as @Peter mentioned, this is related to some deep theory of modular $j$-functions and Heegner numbers, e.g. see Wikipedia and this MSE question. Anyway, the main reason is that we have
$$
e^{\pi \sqrt{163}} \approx 640320^3 + 744
$$
with an error $< 10^{-12}$, so
$$
e^{\frac{\pi\sqrt{163}}{3}} \approx (640320^3 + 744)^{1/3} = 640320 \cdot \left(1 + \frac{744}{640320^3}\right)^{1/3} \approx 644320
$$
where the last approximation is due to
$$
\left(1 + \frac{744}{640320^3}\right)^{1/3} \approx (1 + 3 \cdot 10^{-15})^{1/3} \approx 1 + 10^{-15}.
$$