Consider the field $\mathbb R$ of real numbers under the usual addition and multiplication operations. Can this field be equipped with a total order $\prec$ which is not equal to the usual one $<$, and which gives $\mathbb R$ the structure of an ordered field? If so, is it possible that $(\mathbb R,+,\cdot,\prec)$ is not even isomorphic to $(\mathbb R,+,\cdot,<)$? I believe the second question is equivalent to asking whether there is an ordered field with the same set and binary operations as the real numbers, but which is not Dedekind-complete.
Some progress
Any total order $\prec$ must satisfy $0\prec n$ for every $n\in\mathbb Z^+$. From this, it follows that any total order must satisfy $0\prec r$ for every positive rational (here, I mean "positive" in the sense of the usual ordering). Moreover, if $p,q\in\mathbb Q$, then $p\prec q$ is equivalent to $0\prec q-p$, which in turn is equivalent to $0<q-p$ and thus $p<q$. This means that any total order on $\mathbb R$ agrees with the usual one, as far as rational numbers are concerned.