For a slightly different approach from the other two answers.
Theorem. Suppose that $\{A\subseteq\Bbb R\mid |A|=\aleph_0\}$ can be linearly ordered, then there is a set of real numbers which is not Lebesgue measurable.
First notice that $\Bbb R$ injects into $\{A\subseteq\Bbb R\mid|A|=\aleph_0\}$. If $x\in\Bbb R$ is irrational map it to $\Bbb Q\cup\{x\}$, otherwise map it to $\Bbb Q\setminus\{x\}$. So the set is provably, at least as large as $\Bbb R$.
Now, by cardinal arithmetic, we have that $2^{\aleph_0}=2^{\aleph_0\cdot\aleph_0}=(2^{\aleph_0})^{\aleph_0}$. Therefore the set $\Bbb{R^N}$, of all infinite sequences of real numbers, has the same cardinality as $\Bbb R$. Now, if $f\colon\Bbb{N\to R}$ is any function, if the image of $f$ is infinite, then it is a countably infinite set.
So, we can map $f$ to its image if that image is finite, and if not, just map it to $\Bbb N$ itself. Since $A$ being a countable set means that there is a bijection $f\colon\Bbb N\to A$, the function we have just described is a surjection from $\Bbb R$ onto $\{A\subseteq\Bbb R\mid|A|=\aleph_0\}$, which of course defines a partition of $\Bbb R$.
Finally, if that all sets are Lebesgue measurable, the latter set cannot be linearly ordered. In particular, it is impossible to find an injection from it into the real numbers (since that would allow us to define a linear ordering). So that partition must be strictly larger than $\Bbb R$.