Paul Sinclair has already explained (1)-(3) in the comments, and Mostafa Ayaz has already written up a complete answer but perhaps I can add a few comments and simplifications: this link Are there other kinds of bump functions than $e^\frac1{x^2-1}$? provides many examples/explanations of smooth bump functions (meaning they are $0$ outside of a bounded/compact set).
Pick your favorite one, and call it $\varphi$, and suppose it is supported on $[-B,B]$ (for example, you could pick $\varphi(x) = e^{1/(x^2-1)}$ which is supported on $[-1,1]$). Its integral, say $I$, is some finite positive number. Now remember that I can rescale a function $[x \mapsto f(x)]$ by $[x \mapsto f(ax)]$ (which if you look at the graph has the behavior of contracting the $x$-axis by a factor of $a$), and shift a function $[x\mapsto f(x)]$ by $[x \mapsto f(x-b)]$ (which if you look at the graph has the behavior of moving the graph right by $b$ units). Putting these actions together, we have that $\varphi_1(x):=2\varphi(4(x-2B))$ is $\varphi$ but 4-times skinnier, 2-times taller (hence the integral is $\frac 12$ that of $\varphi$), and centered at $2B$ instead of $0$ (hence its support does not overlap with the support of $\varphi$).
More generally, repeating this process (4-times skinnier and 2-times taller than the previous --- hence area/integral half that of the previous --- and shifted to the right $2B$ units compared to the previous), we get for every positive integer $k$ the function $\varphi_k(x):=2^k \varphi(4^k(x-2Bk))$. And the function whose graphs looks like all these bumps all on one picture is exactly the sum $\Phi:=\varphi + \varphi_1 + \varphi_2 + \ldots$ (the infinite sum is well-defined because for each $x\in \mathbb R$, at most one $\varphi_i$ is non-zero). The integral of this sum function is $I + \frac 12 I+ \frac 14 I + \ldots = 2I$, which is still a finite positive number of course.
If we insist that the resulting function be strictly positive, we can always add a strictly positive function with finite integral, say a Gaussian $e^{-x^2}$. Then the function $\Phi(x)+e^{-x^2}$ is strictly positive and has finite integral $I'$, so normalizing we get the function $\frac{1}{I'} (\Phi(x)+e^{-x^2})$ that is a counterexample to (1)-(3).
Finally for (4), one can pursue the FTC route Mostafa Ayaz takes, or a more geometric approach: again, let us suppose for sake of contradiction that $f''$ is never $0$. Then because $f$ is smooth, $f''$ is continuous, so by the intermediate value theorem, if $f''$ takes different signs, then there is a point at which $f''$ is $0$; contradiction. So then $f$ is either convex or concave (this equivalence between infinitessimal information, i.e. second derivative being $\geq 0$ or $\leq 0$, vs. global information, i.e. the secant line definition of convex/concave, does take a little bit of work; see e.g. If $f$ is a twice differentiable convex function on $\mathbb R$ then show that $f''$ is non negative on $\mathbb R$.).
But concave/convex functions lie above/below their tangent lines (Convexity of a Function Implies Function Lies Above Any Tangent Line):
- if $f$ lies above its tangent lines, then if the tangent line $L(x)$ has non-zero slope, then the positive area under the line (i.e. the integral of $\max\{0,L(x)\}$ on $\mathbb R$) will be infinite; contradiction. So that means that every tangent line to $f$ must have zero-slope, i.e. $f'(x)=0$ for all $x\in \mathbb R$, which by Rolle's theorem implies that $f$ is constant. But constant functions either have integral on $\mathbb R$ equal to $0$ or $\pm \infty$; contradiction.
- if $f$ lies below its tangent lines, then if the tangent line $L(x)$ has non-zero slope, then the negative area under the line (i.e. the integral of $\min\{0,L(x)\}$ on $\mathbb R$) will be (negative) infinite; contradiction. Again this means $f'\equiv 0$, which we already said was a contradiction.
Finally, I remark that one can prove (4) even if $f$ is just twice differentiable; instead of using IVT in the case that $f''$ is continuous, one uses the fact that $f''$ is a derivative of a differentiable function, and hence satisfies the IVT even if it might not be continuous, by Darboux's theorem.